- Hitomi Shizuki (志筑 仁美 Shizuki Hitomi?)
- Voiced by: Ryōko Shintani (Japanese), Shelby Lindley (English)
- Madoka and Sayaka's classmate and friend, although she sometimes
feels left out of Madoka and Sayaka's friendship. Hitomi is quite popular amongst boys. At one point in the plot, she and numerous other people are possessed by a witch named H.N. Elly/Kirsten, and attempt to commit suicide by entering a mostly sealed warehouse and starting a reaction of bleach and ammonia, producing chlorine gas. Madoka, who throws the reaction container out a window before anyone is killed, saves her life just before getting caught in the witch's labyrinth, where she is further rescued by Sayaka when she arrives to kill the witch and save Madoka.
- It is later revealed that she is also in love with Kyosuke, and her
confidence in being able to confess her feelings only contributes to Sayaka's despair. She is later seen at Sayaka's funeral, clutching Kyosuke's shoulder and crying, and is said to have blamed herself for Sayaka's death. In Rebellion, she suffers from sadness and anger because hers and Kyōsuke's schedules were different, thus creating an Nightmare from her emotions.